Multicolor Photochromism of Two- and Three-Component Diarylethene Crystals
Masakazu Morimoto, Seiya Kobatake, and Masahiro Irie
J. Am. Chem. Soc., 125, 11080-11087 (2003)
Novel photochromic single crystals composed of three different kinds
of diarylethenes, 1,2-bis(3,5-dimethyl-2-thienyl)perfluorocyclopentene
(1a), 1,2-bis(2,5-dimethyl-3-thienyl)perfluorocyclopentene (2a), and 1,2-bis(2-methyl-5-p-methoxyphenyl-3-thienyl)perfluorocyclopentene
(3a), have been prepared. The three-component crystals turned yellow, orange,
red, purple, blue, green, or black upon irradiation with light of appropriate
wavelengths. The colors of the crystals were thermally stable in the dark
and completely bleached by irradiation with visible light. Such multicolored
photochromic crystals have potential for the application to optoelectronic
devices, such as multifrequency three-dimensional optical memory media
or full-color displays.
(2a)
(3a)