永野 修作 Shusaku NAGANO
立教大学 理学部 化学科 教授
Professor
Department of Chemistry, College of Science, Rikkyo University
| Research Intersts: | 分子配向によるイオン伝導性制御 導電性高分子ナノネットワーク形成と非線形応答 新たな液晶性ラメラ構造の形成と機能化 ソフトマテリアルの配向機能材料 ミクロ相分離構造の光配向制御 - 液晶性アゾベンゼンブロックコポリマー 高分子主鎖の配向制御 - 高分子半導体, 液晶性高分子 高分子超薄膜 - 高分子単分子膜, 液晶性高分子グラフト膜 メソポーラス材料の配向制御（ゾル－ゲル法） 液晶光配向技術, 表面配向制御, 高分子材料の屈折率制御, 液晶/高分子ハイブリッド Including Photoconductive Devices, Thin-Film Field-Effect Transistors, Nonlinear Optical Properties, Photolysis ... and more -高分子合成（ATRP, 表面開始ATRP, ROMP, 表面開始ROMP）, 導電性高分子合成 -X線散乱測定(SAXS, WAXS), 斜入射X線散乱測定(GI-SAXS, GI-WAXS) -Langmuir-Blodgett technique, 高分子分光測定, AFM |
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| Technical Fields: | 光機能性高分子, 高分子半導体, 高分子液晶, 高分子表面・界面, 高分子超薄膜, 光化学, 高分子合成 |
| Lectures & Classes | 反応速度論（2020年～） 化学実験B（2020年～） 化学実験C（2021年～） 基礎化学実験（2020年～2021年） 物理化学３（2020年～） 化学の最前線（2020年～） 身近な物質の化学（2020年～） 自然科学の探求（2021年～2023年） 物理化学応用特論２（2020年～） 物理化学基礎特論（2021年～）
名古屋大学講義 機能性高分子薄膜の分子配向と解析に関する講義 (高分子組織化学) 量子化学2 (2016年- 多電子原子、化学結合、分子分光学など) 原子・分子の化学 (2012年-2016年 大気汚染、温暖化、水質など) Polymer Chemistry (2014年-2015年 organized structure of polymers) 実験安全学(2014年) 化学生命工学実験(2019年) 化学実験(2019年) 無機・物理化学実験(～2012年) 物理化学実験(～2012年) |
| Location: | 4号館4123室 |
| Academic Education: | 平成3年3月 神奈川県立希望ヶ丘高等学校卒業 平成7年3月 学習院大学理学部化学科卒業 平成7年4月 学習院大学大学院自然科学研究科化学専攻博士前期課程入学 平成9年3月 同大学大学院 博士前期課程修了 平成10年4月 東京工業大学大学院総合理工学研究科物質化学創造専攻 博士課程入学 （資源化学研究所 光機能化学部門） 平成13年3月 同大学大学院 博士課程修了 博士（工学） |
| Professional Experience： | 平成9年4月 日本パーカライジング株式会社 総合技術研究所 研究員 平成13年4月 株式会社リコー 中央研究所 研究員 平成14年11月 名古屋大学大学院工学研究科 助手 平成19年4月 呼称変更により 同上 助教 平成21年10月-平成25年3月 日本学術振興機構 さきがけ研究「ナノシステムと機能創発」研究者 平成23年8月 名古屋大学ベンチャービジネスラボラトリー 准教授 令和2年 立教大学理学部化学科 教授 現在に至る |
| Awards: | 2017年 平成29年度高分子学会日立化成賞 2016年 平成27年度(第33回)永井科学技術財団賞（奨励賞） 2015年 日本液晶学会論文賞（A部門） 2009年 東海化学工業会賞（学術） 2009年 日本化学会第８９春季年会（２００９）優秀講演賞（産業） 2008年 日本液晶学会論文賞（A部門） 2007年 高分子学会研究奨励賞 2000年 日本MRS奨励賞、2003年日本MRS奨励賞 |
| My Favorites: | Fast Cars, Heavy Rock, Electric Guitars MEGADETH, Def Leppard, ZZ top, George Lynch, Paul Gilbert, Nikon FE and Ricoh GRIV |
| Affiliation: | 高分子学会, 日本液晶学会, 応用物理学会, 日本化学会, アメリカ化学会 |
| Extramural Activities: | 教育活動： 令和5年度 大分大学非常勤講師 令和4年度 東京工業大学非常勤講師 平成29年度 山形大学非常勤講師 平成27年度 三重大学大学院非常勤講師 楽しい実験教室 「高分子を見よう、作ろう、使おう」-ナノテク・バイオ・環境科学と高分子—実験教室：光重合-ハイドロゲルを作る-, 2015年 愛知県高等学校文化連盟 名古屋大学 化学・生物実験講習会 , 2008年08月 ～ 2012年08月 四日市高校 スーパーサイエンスハイスクール , 2003年08月 ～ 2005年08月
学会活動： 高分子学会 男女共同参画委員(2022年～) 高分子学会「高分子」編集員(2017年～2019年) 日本液晶学会 行事担当理事 (2017年～2019年) 日本液晶学会 代議員 (2016年～ 2017年) 応用物理学会 有機分子・バイオエレクトロニクス分科会 プログラム編成委員 (平成25年度～) 日本液晶学会 液晶化学・材料フォーラム 委員 (平成21年度～28年, 平成23年度主査） 応用物理学会 有機分子・バイオエレクトロニクス分科会 幹事 (平成23年度～平成24年度) 高分子学会 第59回高分子討論会 特定テーマセッションオーガナイザー(2020年) 日本液晶学会 液晶光デバイス・フォトニクスフォーラム 会計（平成21～22年度） 高分子学会東海支部 東海高分子研究会平成26年度 代表幹事 高分子学会東海支部 東海高分子研究会平成21年度 講演会幹事 高分子学会東海支部 東海高分子研究会平成20年度 庶務幹事 高分子学会東海支部 東海高分子研究会平成18年度 講演会幹事 高分子学会東海支部 東海高分子研究会平成17年度 夏期合宿幹事 第2回ソフトマテリアルの光配向と光パターニングの国際会議（PhoSM2016, 2016/11/24-27, 名古屋大学）委員 第21回先端ディスプレイ材料とデバイスの国際会議（ADMD2017, 2017/7/24-26, 名古屋大学）委員 KJF International Conference on Organic Materials for Electronics and Photonics (KJF ICOMEP 2018) 委員
共用設備サポート： 文科省「ナノテクノロジープラットフォーム」・名古屋大学設備・機器共用推進室 微細加工プラットフォーム 分子・物質合成プラットフォーム(XRD, AFM, GI-SAXS, 各種分光)
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Publications
Recent Reviews
| 1 | S. Nagano, "Random planar orientation in liquid-crystalline block copolymers with azobenzene side chains by surface segregation", Langmuir, 35, 5673-5683 (2019). 10.1021/acs.langmuir.8b01824
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| 2 | 篠原 佑也, 永野 修作, "斜入射X線散乱測定による薄膜の配向構造評価", 液晶, 22(4), 246-255 (2018). |
| 3 | S. Nagano, "Surface and interface designs in side-chain liquid crystalline polymer systems for photoalignment", Polymer Journal, 50, 1107–1119 (2018).
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| 4 | 永野 修作, "ミクロ相分離構造を光で並べる、動かす", 高分子, 67(6), 324 (2018). |
| 5 | S. Nagano, “Inducing Planar Orientation in Side‐Chain Liquid‐Crystalline Polymer Systems via Interfacial Control”, Chem. Rec., 16, 378-392 (2016). DOI: 10.1002/tcr.201500232
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| 158 |
M. Inoue, R. Sakashita, S. Kagaya, M. Gemmei-Ide, Y. Yao, A. Suwansoontorn, S. Nagano, S. Yamamoto, M. Mitsuishi, Y. Nagao, J. Matsui, "Mechanism of High Proton Mobility in the Two-Dimensional Nanospace at the Interlayer of a Multilayer Polymer Nanosheet Film," The Journal of Physical Chemistry C, 127 (50), 24046-24055 (2023). |
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| 157 |
M. S. Grewal, K. Ishibashi, M. Hara, Y. Ishizaki, S. Nagano, H. Yabu, "Effect of the Poly (ethylene glycol) Diacrylate (PEGDA) Molecular Weight on Ionic Conductivities in Solvent-Free Photo-Cross-Linked Solid Polymer Electrolytes," Langmuir, 39 (29), 10209-10215 (2023). |
| 156 |
Y Yao, H Watanabe, M Hara, S Nagano, Y Nagao, "Lyotropic Liquid Crystalline Property and Organized Structure in High Proton-Conductive Sulfonated Semialicyclic Oligoimide Thin Films," ACS Omega, 8 (8), 7470-74781 (2023). |
| 155 | M Hara, A Masuda, S Nagano, T Seki, "Photoalignment and Photofixation of Chromonic Mesophase in Ionic Linear Polysiloxanes Using a Dual Irradiation System," Crystals, 13 (2), 326 (2023). |
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154
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M. Ohke, R. Akaishi, K. Tachibana, M. Kohri, S. Nagano, H. Ebe, J. Matsui, "Janus metallic film with gold and silver luster by electroless deposition of silver using poly (dopamine acrylamide) thin film," RSC Advances, 13 (40), 28104-28111 (2023). |
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153
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M Kikuchi, N Saito, M Ohke, S Nagano, S Nishitsuji, J Matsui, "Order–order transitions in poly (N-octadecyl acrylamide-co-hydroxyethyl acrylamide) statistical copolymer filmsm," Soft Matter, 19 (17), 3058-3068 (2023). |
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152
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N Hida, T Nakajima, M Hara, T Seki, S Nagano, "Induced Smectic E Phase in a Binary Blend of Side‐Chain Liquid Crystalline Polymers," Macromol. Rapid Commun., 2200761 (1 of 5) (2023). doi.org/10.1002/marc.202200761 |
2022
| 151 |
Y. Minowa, Y. Yabuuchi, S. Nagano, S. Nagamatsu, A. Fujii, M. Ozaki, "Fast-Coating Process Based on Elongated Rodlike Preaggregate for Highly Oriented Thin Film of Donor–Acceptor π-Conjugated Polymer," ACS Appl. Mater.Interfaces, 14, 44, 50112–50119 (2022).
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| 150 |
M. Furuichi, M. Hara, S. Nagano, T. Seki, "The Effect of a Topcoat with Amorphous Polymer Layers on the Mesogen Orientation and Photoalignment Behavior of Side Chain Liquid Crystalline Polymer Films," Appl. Sci., 12 (19), 9410 (2022). |
| 149 |
F. Wang, S. Nagano, M. Hara, Y. Nagao, "Hydration and OH–/Br– Conduction Properties of Fluorene–Thiophene-Based Anion Exchange Thin Films Tethered with Different Cations," ACS Appl. Polym. Mater., 4 (8), 5965-5974 (2022). |
| 148 |
M. Hara, A. Kodama, S. Washiyama, Y. Fujii, S. Nagano, T. Seki, "Humidity-Induced Self-Assembled Nanostructures via Ion Aggregation in Ionic Linear Polysiloxanes," Macromolecules, 55, 11, 4313–4319 (2022). |
| 147 |
M Hara, R Oguri, S Sarkar, S Nagano, T Seki, "Crystallization-Induced Uniform Nanodot Formation of Titanium Dioxide Films," Bull. Chem. Soc. Jpn., 95 (2), 216-220 (2022). |
| 146 |
S. Okuda, N. Ousaka, T. Iwata, R. Ishida, A. Urushima, N. Suzuki, S. Nagano, T. Ikai, E. Yashima, "Supramolecular Helical Assemblies of Dirhodium(II) Paddlewheels with 1,4-Diazabicyclo[2.2.2]octane: A Remarkable Substituent Effect on the Helical Sense Preference and Amplification of the Helical Handedness Excess of Metallo-Supramolecular Helical Polymers,"J. Am. Chem. Soc., 144, 6, 2775–2792 (2022).
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| 145 |
S. Ghosh, Y. Tsutsui, T. Kawaguchi, W. Matsuda, S. Nagano, K. Suzuki, H. Kaji, S. Seki, "Band-like Transport of Charge Carriers in Oriented Two-Dimensional Conjugated Covalent Organic Frameworks," Chem. Mater., 34, 2, 736–745 (2022).
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| 144 |
K. Onishi, S. Ohtani, K. Kato, S. Fa, Y. Sakata, S. Akine, M. Ogasawara, H. Asakawa, S. Nagano, Y. Takashima, M. Mizuno, T. Ogoshi,"State-and water repellency-controllable molecular glass of pillar [5] arenes with fluoroalkyl groups by guest vapors,"Chem. Sci., 13, 4082-4087 (2022).
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| 143 |
C. Hayasaka, S.Nagano, K. Nakano,"Synthesis of π-extended oxacenes and their application to organic field-effect transistors," Organic Electronics, 100, 106335 (1-8) (2022). |
| 142 |
K. Mukai, M. Hara, H. Yabu, S. Nagano, T. Seki, "Photoswitchable Configuration of Nematic Liquid Crystal Droplets Embedded in a Honeycomb-Patterned Film," Adv. Mater. Interfaces, 2100891 (1-8) (2021). |
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| 141 |
S. Fa, M. Mizobata, S. Nagano, K. Suetsugu, T. Kakuta, T. Yamagishi, T. Ogoshi, "Reversible “On/Off” Chiral Amplification of Pillar [5] arene Assemblies by Dual External Stimuli," ACS Nano, 15, 10, 16794–16801 (2021). |
| 140 |
M. Hara, Y. Iijima, S. Nagano, T. Seki, "Simple linear ionic polysiloxane showing unexpected nanostructure and mechanical properties," Sci. Rep. 11, 17683 (1-8) (2021). |
| 139 |
Y. Yabuuchi, Y. Minowa, H. Kajii, S. Nagano, A. Fujii, M. Ozaki, "Direction‐Selectable Ultra‐Highly Oriented State of Donor–Acceptor Conjugated Polymer Induced by Slow Bar Coating Process," Adv. Electronic Mater., 7, 2100313 (2021). |
| 138 |
I. Kitamura, M. Hara, S. Nagano, T. Seki, "Photo-triggered surface relief formation of polystyrene films based on the Marangoni flow driven by a surface photoresponsive skin layer," Mol. Cryst. Liq. Cryst., accepted (2021). |
| 137 |
R. Goto, Y. Ono, M. Hara, T. Seki, Y. Nagao, S. Nagano, "Preparation and structural characterization of shear-aligned films in a high proton conductive alkyl-sulfonated polyimide with lyotropic liquid crystallinity," Mol. Cryst. Liq. Cryst., accepted (2021). |
| 136 |
K. Koseki, T. Arita, K. Tabata, T. Nohara, R. Sato, S. Nagano, A. Masuhara, "Effect of Surface Silanol Density on the Proton Conductivity of Polymer-Surface-Functionalized Silica Nanoparticles," ACS Sustainable Chem. & Eng., 9, 10093-10099 (2021). |
| 135 |
A. Suwansoontorn, K. Yamamoto, S. Nagano, J. Matsui, Y. Nagao, "Interfacial and Internal Proton Conduction of Weak-acid Functionalized Styrene-based Copolymer with Various Carboxylic Acid Concentrations," Electrochemistry, 89, 401-408 (2021). |
| 134 |
R Yamakado, I Kitamura, M Hara, S Nagano, T Seki, H Maeda, "Photoisomerization-induced patterning of ion-pairing materials based on anionic azobenzene and its complex with a fluorescent π-electronic system," Chem. Commun., 57 , 4287-4290 (2021). |
| 133 |
G. Uzurano, Y. Yabuuchi, R. Ishiura, M. Yoneya, S. Nagano, H. Kajii, A. Fujii, M. Ozaki, "Molecular orientation and electrical properties in tert‐butylated phthalocyanine thin film fabricated by uniaxial solution coating," Electronics and Communications in Japan, 140, 11, 1182-1188 (2021). |
| 132 |
K. Matsunaga, W. Kukai, M. Ishizaki, M. Kurihara, S. Yamamoto, M. Mitsuishi, H. Yabu, S. Nagano, J. Matsui, "Formation of Perpendicularly Aligned Sub-10 nm Nanocylinders in Poly(N-dodecylacrylamide-b-ethylene glycol) Block Copolymer Films by Hierarchical Phase Separation," Macromolecules, 53, 21, 9601–9610 (2020). |
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| 131 |
T. Nishida, K. Satoh, S. Nagano, T. Seki, M. Tamura, Y. Li, K. Tomishige, M. Kamigaito, "Biobased Cycloolefin Polymers: Carvone-Derived Cyclic Conjugated Diene with Reactive exo-Methylene Group for Regioselective and Stereospecific Living Cationic Polymerization," ACS Macro Lett., 9, 1178-1183 (2020). |
| 130 |
I. Kitamura, K. Kato, R.B. Berk, T. Nakai, M. Hara, S. Nagano, T. Seki, "Photo-triggered large mass transport driven only by a photoresponsive surface skin layer," Sci. Rep., 10 (1), 1-10 (2020). |
| 129 |
M. Hara, N. Wakitani, A. Kodama, S. Nagano, T. Seki, "Hierarchical photocomposition of hetero-nanostructures in a surfactant-polysiloxane hybrid film toward next-generation nanolithography," ACS Appl. Polym. Mater., 2, 6, 2284–2290 (2020). |
| 128 |
R. Imanishi, Y. Nagashima, K. Takishima, M. Hara, S. Nagano, T. Seki, "Induction of Highly Ordered Smectic Phases in Side Chain Liquid Crystalline Polymers by Means of Random Copolymerization,"Macromolecules, 53 (6), 1942-1949 (2020). |
| 127 |
U. N. Shrivastava, K. Suetsugu, S. Nagano, H. Fritzsche, Y. Nagao, K. Karan, "Cross-correlated humidity-dependent structural evolution of Nafion thin films confined on a platinum substrate," Soft Matter, 16 (5), 1190-1200 (2020). |
| 126 |
K. Ebata, Y. Hashimoto, S. Yamamoto, M. Mitsuishi, S. Nagano, J. Matsui, "Nanophase Separation of Poly(N-alkyl acrylamides): The Dependence of the Formation of Lamellar Structures on Their Alkyl Side Chains," Macromolecules, 52 (24), 9773-9780 (2019). |
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| 125 |
Y. Yabuuchi, G. Uzurano, R. Ishiura, M. Nakatani, S. Nagano, A. Fujii, M. Ozaki, "Coating speed dependence of main chain orientation and aggregation of PBTTT-C16 in the bar-coated thin film," J. J. Appl. Phys., 59 (SD), SDDA04 (2019). |
| 124 |
G. Uzurano, Y. Yabuuchi, R. Ishiura, M. Yoneya, S. Nagano, A. Fujii, M. Ozaki, "Solution processed uniaxially oriented thin film of tert-butyl-substituted phthalocyanine," J. J. Appl. Phys., 59 (SD), SDDA05 (2019). |
| 123 |
Y. Tsujimoto, T. Sakurai, Y. Ono, S. Nagano, S. Seki, "Cold Crystallization of Ferrocene-Hinged π-Conjugated Molecule Induced by the Limited Conformational Freedom of Ferrocene," J. Phys. Chem. B, 123 (39), 8325-8332 (2019). |
| 122 |
K Mukai, M Hara, S Nagano, T Seki, "Formation of High-Density Brush of Liquid Crystalline Polymer Block Associated with Dewetting Process on Amorphous Polymer Film", Langmuir, 35 (32), 10397-10404 (2019). DOI：10.1021/acs.langmuir.9b01689 |
| 121 |
T. Kitagawa, M. Fujisaki, S. Nagano, N. Tohnai, A. Fujii, M. Ozaki, "Homo/hetero-epitaxial growth in tetrabenzotriazaporphyrin derivative thin film fabricated by contact freezing method with seed crystal", Appl. Phys. Express 12 (5), 05101 (2019). |
| 120 |
R. Yamakado, Y.Haketa, M. Hara, S. Nagano, T. Seki, H. Maeda, "Photo-responsive dimension-controlled ion-pairing assemblies based on anion complexes of π-electronic systems", Chem. Commun. DOI: 10.1039/C9CC05632G |
| 119 |
K. Mukai, K. Imai, M. Hara, S. Nagano, T. Seki, "A High‐Density Azobenzene Side Chain Polymer Brush for Azimuthal and Zenithal Orientational Photoswitching of a Nematic Liquid Crystal", ChemPhotoChem, 3, 495-500 (2019) DOI:10.1002/cptc.201800234 |
| 118 |
I. Kitamura, K. Oishi, M. Hara, S. Nagano, T. Seki, "Photoinitiated Marangoni flow morphing in a liquid crystalline polymer film directed by super-inkjet printing patterns", Sci. Rep., 9, 2556 (2019). DOI: 10.1038/s41598-019-38709-1 |
| 117 |
Y. Nagao, T. Tanaka, Y. Ono, K. Suetsugu, M. Hara, G. Wang, S. Nagano, T. Abe, "Introducing planar hydrophobic groups into an alkyl-sulfonated rigid polyimide and how this affects morphology and proton conductivity", Electrochimica Acta, 300, 333-340 (2019). DOI: 10.1016/j.electacta.2019.01.118 |
| 116 |
K. Takakura, Y. Ono, K. Suetsugu, M. Hara, S. Nagano, T. Abe, Y. Nagao, "Lyotropic ordering for high proton conductivity in sulfonated semialiphatic polyimide thin films", Polymer Journal, 51, 31–39 (2019). DOI: 10.1038/s41428-018-0111-1 |
| 115 |
K. Ebata, Y. Hashimoto, K. Ebara, M. Tsukamoto, S. Yamamoto, M. Mitsuishi, S. Nagano, J. Matsui, "Molecular-weight dependence of the formation of highly ordered lamellar structures of poly (N-dodecyl acrylamide) by humid annealing", Polymer Chemistry, 10 (7), 835-842 (2019). DOI: 10.1039/C8PY01660G |
| 114 |
R. Imanishi, Y. Nagashima, M. Hara, S. Nagano, T. Seki, "Collective Competition between Two Mesogens showing Opposing Orientational Nature in Side Chain Liquid Crystalline Polymers", Chemistry Letters, 48 (2), 98-101 (2018). DOI: 10.1246/cl.180879 |
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| 113 |
M. Nakatani, M. Ohmori, S. Nagano, A. Fujii, M. Ozaki, "Selective crystal growth in bar-coating process of polymorphic pentyl-substituted phthalocyanine thin film", Organic Electronics, 62, 241-247 (2018). DOI: 10.1016/j.orgel.2018.08.019 |
| 112 |
K. Takagi, S. Yamamoto, K. Tsukamoto, Y. Hirano, M. Hara, S. Nagano, Y. Ie, D. Takeuchi,"Synthesis and Field‐Effect Transistor Application of π‐Extended Lactam‐Fused Conjugated Oligomers obtained by Tandem Direct Arylation", Chemistry–A European Journal, 24 (53), 14137-14145 (2018). DOI: 10.1002/chem.201801399 |
| 111 |
K. Yoshikawa, D. Motoyama, Y. Hiruma, H. Ozawa, S. Nagano, M. Haga, "Proton-Rocking-Chair-Type Redox Capacitors Based on Indium Tin Oxide Electrodes with Multilayer Films Containing Ru Complexes", ACS applied materials & interfaces, 10 (32), 26990-27000 (2018). DOI: 10.1021/acsami.8b05907 |
| 110 |
R. Imanishi, M. Hara, S. Nagano, T. Seki, "Photocontrol of mesogen alignment in a side chain LC polymer film by means of random copolymerization of two mesogens of opposing orientation nature", Molecular Crystals and Liquid Crystals, 663 (1), 99-107 (2018). DOI: 10.1080/15421406.2018.1468136 |
| 109 |
Y. Ono, R. Goto, M. Hara, S. Nagano, T. Abe, Y. Nagao, High Proton Conduction of Organized Sulfonated Polyimide Thin Films with Planar and Bent Backbones, Macromolecules, 51 (9), 3351-3359 (2018). DOI: 10.1021/acs.macromol.8b00301 |
| 108 |
R. Yamakado, M. Hara, S. Nagano, T. Seki, H. Maeda, "Complexation of Anion-responsive π-Electronic System with Alkyl-substituted Azobenzene Carboxylate Providing Ion-pairing", Chemistry Letters, 47(4), 404-407 (2018). DOI: 10.1246/cl.171128. |
| 107 |
H. Yabu, S. Nagano, Y. Nagao, "Core-shell cylinder (CSC) nanotemplates comprising mussel-inspired catechol-containing triblock copolymers for silver nanoparticle arrays and ion conductive chan", RSC Advances,8 (19), 10627-10632 (2018). DOI: 0.1039/C8RA00630J |
| 106 |
T. Sakurai, N. Orito, S. Nagano, K. Kato, M. Takata, S. Seki, "Electron-transporting foldable alternating copolymers of perylenediimide and flexible macromolecular chains", Materials Chemistry Frontiers,2 (4), 718-729 (2018).DOI: 10.1039/C7QM00616K |
| 105 |
M. Hara, T. Orito, S.Nagano, T. Seki, "Humidity-responsive phase transition and on-demand UV-curing in a hygroscopic polysiloxane–surfactant nanohybrid film", Chem. Commun., 54, 1457-1460 (2018). DOI: 10.1039/C7CC09226A |
| 104 |
T. Sato, M. Tsukamoto, S. Yamamoto, M. Mitsuishi, T. Miyashita, S. Nagano, J. Matsui, "Acid-Group-Content-Dependent Proton Conductivity Mechanisms at the Interlayer of Poly (N-dodecylacrylamide-co-acrylic acid) Copolymer Multilayer Nanosheet Films", Langmuir, 33 (45), 12897–12902 (2017).doi.10.1021/acs.langmuir.7b03160 |
|---|---|
| 103 |
K. Ogawa, M. Hara, S. Nagano, T. Seki, Y. Takeoka, "Photo-tunable Christiansen Colour Filter Using Photoisomerization of Stilbene", Chem. Lett., 46(9), 1386-1389 (2017). doi.org/10.1246/cl.170603 |
| 102 |
T. Seki, K. Fukuhara, D. Tanaka, T. Nakai, M. Hara, S. Nagano, "Free surface command layers for the photoalignment", Molecular Crystals and Liquid Crystals,653 (1), 1-8 (2017). |
| 101 |
T. Sakaguchi, S. Nagano, M. Hara, S. H. Hyon, M. Patel, K. Matsumura, "Facile preparation of transparent poly (vinyl alcohol) hydrogels with uniform microcrystalline structure by hot-pressing without using organic solvents", Polym. J., 49, 535–542 (2017). |
| 100 |
H. Yabu, S. Nagano, "Formation of unusual microphase-separated ultrathin films of poly (vinyl catechol-block-styrene)(PVCa-b-PSt) at the air–water interface by solution casting onto water", RSC Adv., 7, 33086-33090 (2017). |
| 99 |
R. Yamakado, M. Hara, S. Nagano, T. Seki, H. Maeda, "Photo‐Responsive Soft Ionic Crystals: Ion‐Pairing Assemblies of Azobenzene Carboxylates", Chem. Eur. J., 23, 9244–9248 (2017). 10.1002/chem.201701925 |
| 98 |
K Beppu, Y Nagashima, M Hara, S Nagano, T Seki, "Photoalignment of Vertically Oriented Microphase Separated Lamellae in LC–LC Diblock Copolymer Thin Film", Macromol. Rapid Commun., 38, 1600659 (2017). |
| 97 |
K. Mukai, K. Imai, M. Hara, S. Nagano, T. Seki, "Liquid Crystal Phase Behavior of a Polymer Brush Film with Azobenzene Side Chains", 高分子論文集, 74 (1), 59-63 (2017). |
| 96 |
T Seki, D Yamaoka, T Takeshima, Y Nagashima, M Hara, S Nagano, "Photo-modulations of surface wrinkles formed on elastomer sheets", Mol. Cryst. Liq. Cryst.644 (1), 52-60 (2017). |
| 95 |
S. Mitsui, S. Nagano, M. Hara, T. Seki, “SRG Inscription in Supramolecular Liquid Crystalline Polymer Film: Replacement of Mesogens”, Crystals, 7, 52(1-10). DOI: 10.3390/cryst7020052 |
| 94 |
Y. Nagao, K. Krishnan, R. Goto, M. Hara, S. Nagano, “Effect of Casting Solvent on Interfacial Molecular Structure and Proton Transport Characteristics of Sulfonated Polyimide Thin Films”, Anal. Sci., 33, 35-39 (2017). DOI: 10.2116/analsci.33.35 |
| 93 |
Y. Hashimoto, T. Sato, R. Goto, Y. Nagao, M. Mitsuishi, S. Nagano, J. Matsui, “In-plane oriented highly ordered lamellar structure formation of poly (N-dodecylacrylamide) induced by humid annealing”, RSC Adv., 7, 6631-6635 (2017). DOI: 10.1039/C6RA27994E |
| 92 |
T. Motokawa, M. Makino, K. Yamamoto, H. Takase, S. Nagano, Y. Enomoto-Rogers, T. Iwata, T. Kawaguchi, M. Sakaguchi, "Chemical surface modification of aluminum oxide nanoparticles with graft copolymer of aluminum oxide and poly (isobutyl vinyl ether) mechanochemically synthesized in vacuum at low temperature", Adv. Powder Technol., 28, 266–279 (2017). DOI: 10.1016/j.apt.2016.09.031 |
2016
| 91 |
K. Mukai, M. Hara, S. Nagano, T. Seki, High-density liquid crystalline polymer brushes formed via surface segregation and self-assembly, Angew. Chem. Int. Ed., 128, 14234-14238 (2016). DOI: 10.1002/ange.201607786. |
|---|---|
| 90 |
H. Yabu, J. Matsui, M. Hara, S. Nagano, Y. Matsuo, Y. Nagao, "Proton Conductivities of Lamellae-Forming Bioinspired Block Copolymer Thin Films Containing Silver Nanoparticles", Langmuir, 32, 9484-9491 (2016). DOI: 10.1021/acs.langmuir.6b02521 |
| 89 |
R. Kurimoto, K. Kanie, K. Uto, S. Kawai, M. Hara, S. Nagano, Y. Narita, H. Honda, M. Naito, M. Ebara, R. Kato, "Combinational Effects of Polymer Viscoelasticity and Immobilized Peptides on Cell Adhesion to Cell-selective Scaffolds", Anal. Sci., 32, 1195-1202 (2016). DOI: 10.2116/analsci.32.1195 |
| 88 |
S. Laokroekkiat, M. Hara, S. Nagano, Y. Nagao, "Metal-Organic Coordination Network Thin Film by Surface-Induced Assembly", Langmuir, 32, 6648-6655 (2016). DOI: 10.1021/acs.langmuir.6b01251 |
| 87 |
R. Kurimoto, K. Kanie, N. Idota, M. Hara, S. Nagano, T. Tsukahara, Y. Narita, H. Honda, M. Naito, M. Ebara, R. Kato"Combinational Effect of Cell Adhesion Biomolecules and Their Immobilized Polymer Property to Enhance Cell-Selective Adhesion", Int. J. Polym. Sci. 2016, 2090985(9) (2016). DOI: 10.1155/2016/2090985 |
| 86 |
M. A. Rashed, S. Laokroekkiat, M. Hara, S. Nagano, Y. Nagao"Fabrication and Characterization of Cross-linked Organic Thin Films with Nonlinear Mass Densities", Langmuir, 32, 5917-5924 (2016). DOI: 10.1021/acs.langmuir.6b00540 |
| 85 |
D. Tanaka, T. Mizuno, M. Hara, S. Nagano, I. Saito, K. Yamamoto, T. Seki, "Evaluations of Mesogen Orientation in Thin Films of Polyacrylate with Cyanobiphenyl Side Chain", Langmuir, 32, 3737-3745 (2016). DOI: 10.1021/acs.langmuir.6b00538
|
| 84 |
Y Saito, T Higuchi, H Jinnai, M Hara, S Nagano, Y Matsuo, H Yabu, “Silver Nanoparticle Arrays Prepared by In Situ Automatic Reduction of Silver Ions in Mussel‐Inspired Block Copolymer Films”, Macromol. Chem. Phys., 217, 721-721 (2016). DOI: 10.1002/macp.201670018 |
| 83 |
K. Takagi, K. Yamauchi, S. Kubota, S. Nagano, M. Hara, T. Seki, K. Murakami, Y. Ooyama, J. Ohshita, M. Kondo, H. Masu, “Fused π-conjugated imidazolium liquid crystals: synthesis, self-organization, and fluorescence properties”, RSC Advances, 6, 9152-9159 (2016). DOI: 10.1039/C5RA25496E |
| 82 |
T. Nakai, D. Tanaka, M. Hara, S. Nagano, T. Seki, Free Surface Command Layer for Photoswitchable Out-of-Plane Alignment Control in Liquid Crystalline Polymer Films, Langmuir, 32, 909–914 (2016). DOI: 10.1021/acs.langmuir.5b04325
|
| 81 |
M. Akai-Kasaya, Y. Okuaki, S. Nagano, T. Mitani, and Y. Kuwahara, Coulomb Blockade in a Two-Dimensional Conductive Polymer Monolayer, Phys. Rev. Lett., 115, 196801 (2015). |
|---|---|
| 80 |
Daisuke Tanaka, Yuki Nagashima, Mitsuo Hara, Shusaku Nagano, Takahiro Seki, Alternation of Side-Chain Mesogen Orientation Caused by the Backbone Structure in Liquid-Crystalline Polymer Thin Films, Langmuir, 31(42), 11379-11383 (2015).
|
| 79 |
Karthik Krishnan, Hiroko Iwatsuki, Mitsuo Hara, Shusaku Nagano, Yuki Nagao, Influence of Molecular Weight on Molecular Ordering and Proton Transport in Organized Sulfonated Polyimide Thin Films, The Journal of Physical Chemistry C,119(38), 21767-21774 (2015). |
| 78 |
Takahiro Takeshima, Wan Liao, Yuki Nagashima, Koichiro Beppu, Mitauo Hara, Shusaku Nagano, Takahiro Seki, Photoresponsive Surface Wrinkle Morphologies in Liquid Crystalline Polymer Films, Macromolecules,48(18), 6378-6384 (2015).
|
| 77 |
Masami Sano, Tomoya Murase, Mitsuo Hara, Shusaku Nagano, Yuya Shinohara, Yoshiyuki Amemiya, Takahiro Seki, Photo-switching Behavior of Microphase Separated Structure in Liquid Crystalline Azobenzene Block Copolymers Possessing Different Poly (alkyl methacrylate) Blocks, Molecular Crystals and Liquid Crystals,617(1), 5-13 (2015). |
| 76 |
Masami Sano, Feng Shan, Mitsuo Hara, Shusaku Nagano, Yuya Shinohara, Yoshiyuki Amemiya, Takahiro Seki, Dynamic photoinduced realignment processes in photoresponsive block copolymer films: effects of the chain length and block copolymer architecture, Soft Matter, 11(29), 5918-5925 (2015).
|
| 75 |
Takahiro Seki, Kei Fukuhara, Masami Sano, Mitsuo Hara, Shusaku Nagano, Photoalignment of liquid crystal polymer films containing mesostructures and a free surface command layer, Molecular Crystals and Liquid Crystals, 614, 1-6 (2015). |
| 74 |
Masami Sano, Mitsuo Hara, Shusaku Nagano, Yuya Shinohara, Yoshiyuki Amemiya, Takahiro Seki, New Aspects for the Hierarchical Cooperative Motions in Photoalignment Process of Liquid Crystalline Block Copolymer Films, Macromolecules, 48(7), 2217-2223 (2015).
|
| 73 |
Daichi Yamaoka, Mitsuo Hara, Shusaku Nagano, Takahiro Seki, Photoalignable Radical Initiator for Anisotropic Polymerization in Liquid Crystalline Media, Macromolecules, 48(4), 908-914 (2015). |
| 72 |
Guanghui Cui, Masamichi Fujikawa, Shusaku Nagano, Keisuke Shimokita, Tsukasa Miyazaki, Shinichi Sakurai, Katsuhiro Yamamoto, Macroscopic Alignment of Cylinders via Directional Coalescence of Spheres along Annealing Solvent Permeation Directions in Block Copolymer Thick Films, Macromolecules, 47(17), 5989-5999 (2014). |
|---|---|
| 71 |
Karthik Krishnan, Tomoaki Yamada, Hiroko Iwatsuki, Mitsuo Hara, Shusaku Nagano, Kazuya Otsubo, Osami Sakata, Akihiko Fujiwara, Hiroshi Kitagawa, Yuki Nagano, Influence of Confined Polymer Structure on Proton Transport Property in Sulfonated Polyimide Thin Films, Electrochemistry, 82(10), 865-869 (2014). |
| 70 |
Kei Fukuhara, Mitsuo Hara, Shusaku Nagano, Takahiro Seki, Free Surface-Induced Planar Orientation in Liquid Crystalline Block Copolymer Films: On the Design of Additive Surface Active Polymer Layer, Molecuar Crystals and Liquid Crystals, 601(1), 11-19 (2014) |
| 69 |
Masami Sano, Shiyuko Nakamura, Mitsuo Hara, Shusaku Nagano, Yuya Shinohara, Yoshiyuki Amemiya, Takahiro Seki, Pathways toward Photoinduced Alignment Switching in Liquid Crystalline Block Copolymer Films, Macromolecules, 47(20), 7178-7186 (2014).
|
| 68 |
Guanghui Cui, Masamichi Fujikawa, Shusaku Nagano, Masami Sano, Hiroshi Takase, Tsukasa Miyazaki, Shinichi Sakurai, Katsuhiro Yamamoto, Perpendicular oriented cylinders via directional coalescence of spheres embedded in block copolymer films induced by solvent annealing, Polymer, 55(6), 1601-1608 (2014). |
| 67 |
Karthik Krishnan, Hiroko Iwatsuki, Mitsuo Hara, Shusaku Nagano, Yuki Nagao, Proton conductivity enchancement in oriented, sulfonated polyimide thin films, Journal of Materials Chemistry A, 2(19), 6895-6903 (2014). |
| 66 |
Kei Fukuhara, Shusaku Nagano, Mitsuo Hara, Takahiro Seki, Free-surface molecular command systems for photoalignment of liquid crystalline materials, Nature Communications, 5, 3320(1-8) (2014).
|
| 65 |
Jin Wook Park, Shusaku Nagano, Seong-Jun Yoon, Tomoki Dohi, Jangwon Seo, Takahiro Seki, Soo Young Park, High Contrast Fluorescence Patterning in Cyanostilbene-Based Crystalline Thin Films: Crystallization-Induced Mass Flow Via a Photo-Triggered Phase Transition, Advanced Materials, 26(9), 1354-1359 (2014). |
| 64 |
Hafiz Ashraful Haque, Mitsuo Hara, Shusaku Nagano, Takahiro Seki, Photoinduced In-plane Motions of Azobenzene Mesogens Affected by the Flexibility of Underlying Amorphous Chains, Macromolecules, 46(20), 8275-8283 (2013). |
|---|---|
| 63 |
Mitsuo Hara, Shusaku Nagano, Takahiro Seki, Spontaneous Formation of Vertically Aligned Lamellae in Thin Films of Block Copolymer-Silica Hybrid Material, Bulletin of the Chemical Society of Japan, 86(10), 1151-1157 (2013). (Selected Paper) |
| 62 |
Guanghui Cui, Satoshi Ohya, Taito Matsutani, Shusaku Nagano, Tomoki Dohi, Shiyuko Nakamura, Shinichi Sakurai, Tsukasa Miyazaki, Katsuhiro Yamamoto, Perpendicular orientation of sub-10 nm channels in polystyrene-b-poly(4-hydroxyl styrene)/PEG oligomer blend thin films, Nanoscale, 5, 6713-6719 (2013). |
| 61 |
M. Akai-Kasaya, Y. Okuaki, S. Nagano, A. Saito, M. Aono, Y. Kuwahara, Isotropic charge transport in highly ordered regioregular poly(3-hexylthiophene) monolayer, Journal of Physics D: Applied Physics, 46(42), 425303(1-7) (2013). |
| 60 |
Hafiz Ashraful Haque, Soutarou Kakehi, Mitsuo Hara, Shusaku Nagano, Takahiro Seki, High Density Liquid Crystalline Azobenzene Polymer Brush Attained by Surface-Initiated Ring Opening Metathesis Polymerization, Langmuir, 29(25), 7571-7575 (2013). |
| 59 |
Kei Fukuhara, Yasuyoshi Fujii, Yuki Nagashima, Mitsuo Hara, Shusaku Nagano, Takahiro Seki, Liquid-Crystalline Polymer and Block Copolymer Domain Alignment Controlled by Free-Surface Segregation, Angewandte Chemie International Edition, 52(23), 5988-5991 (2013).
|
| 58 |
Hafiz Ashraful Haque, Shusaku Nagano, Takahiro Seki, Effect of Flexible Chain Length on the Photoorientation Behavior of Surface-grafted Liquid Crystalline Azobenzene Block Copolymer Brush, Molecular Crystals and Liquid Crystals, in press. |
| 57 |
Wenhan Li, Shusaku Nagano, Koichiro Yonetake,Takahiro Seki, Photoinduced Dewetting in Thin Films of Liquid Crystalline Dendritic Azobenzene Derivatives, Molecular Crystals and Liquid Crystals, 563(1), 112-120 (2012). |
|---|---|
| 56 |
Yuki Hayata, Shusaku Nagano, Yukikazu, Takeoka, Takahiro Seki, Photoinduced Volume Transition in Liquid Crystalline Polymer Gels Swollen by a Nematic Solvent, ACS Macro Letters, 1(11), 1357-1361 (2012). |
| 55 |
Hafiz Ashraful Haque, Shusaku Nagano, Takahiro Seki, Lubricant Effect of Flexible Chain in the Photoinduced Motions of Surface-Grafted Liquid Crystalline Azobenzene Polymer Brush, Macromolecules, 45(16), 6095–6103 (2012). |
| 54 |
Wenhan Li, Tomoki Dohi, Mitsuo Hara, Shusaku Nagano, Osamu Haba, Koichiro Yonetake, Takahiro Seki, Phototriggered Mass Migration Consorted with Surface Dewetting in Thin Films of a Liquid Crystalline Azobenzene-containing Dendrimer, Macromolecules, 45(16), 6618–6627 (2012). |
| 53 |
Shusaku Nagano, Yusuke Koizuka, Tomoya Murase, Masami Sano, Yuya Shinohara, Yoshiyuki Amemiya, Takahiro Seki, Synergy Effect on Morphology Switching: Real-Time Observation of Photo-Orientation of Microphase Separation in a Block Copolymer, Angewandte Chemie International Edition, 51(24), 5884-5888 (2012).
|
| 52 |
Shun-ichiro Watanabe, Hisaaki Tanaka, Shin-ichi Kuroda, Akio Toda, Haruki Tomikawa, Shusaku Nagano, Takahiro Seki, Charge Transport Anisotropy due to Interfacial Molecular Orientation in Polymeric Transistors with Controlled In-Plane Chain Orientation, Applied Physics Express, 5, 021602-021604 (2012). |
| 51 |
Shusaku Nagano, Opto-orientation control of microphase separation structure, Molecular Electronics and Bioelectronics, 22(2), 93-96 (2011). |
|---|---|
| 50 |
Koji Takagi, Takato Isomura, Yohei Ito, Masanori Sakaida, Shusaku Nagano, Takahiro Seki, Synthesis and isomerization of conjugated oligomers containing azoimidazole unit, Journal of Polymer Science, Part A: Polymer Chemistry, 49(23), 4993-5000 (2011). |
| 49 |
Shusaku Nagano, Tetsuya Kinumatsu, Yuki Ohnuma, Takahiro Seki, “Inversed” surface micelle array fabrication of an amphiphilic block copolymer on water surface, Journal of Nanoscience and Nanotechnology, 11(4), 2973-2978 (2011). |
| 48 |
M. Hara, S. Nagano, T. Seki, p-p Interaction-induced Vertical Alignment of Silica Mhannels Templated by a Discotic Lyotropic Liquid Crystal, J. Am. Chem. Soc., 132, 13654-13656 (2010). |
| 47 |
Kenji Aoki, Takafumi Iwata, Shusaku Nagano, Takahiro Seki Light-directed Anisotropic Reorientation of Mesopatterns in Block Copolymer Monolayer, Macromolecular Chemistry and Physics, 211(23), 2484-2489 (2010). (Top cover page featured) |
| 46 |
S. Watanabe, H. Tanaka, S. Kuroda, A. Toda, S. Nagano, T. Seki, A. Kimoto, J. Abe, ”Electron spin resonance observation of field-induced charge carriers in ultrathin-film transistors of regioregular poly(3-hexylthiophene) with controlled in-plane chain orientation”, Appl. Phys. Lett., 96, 173302-173302 (2010). |
| 45 |
K. Ichimura, K. Aoki, H. Akiyama, S. Horiuchi, S. Nagano, S. Horie, “Properties of core-shell structured nanopowders of molecular crystals fabricated by dry grinding”, J. Mater. Chem., 20, 4312-4320 (2010). |
| 44 |
J. Isayama, S. Nagano, T. Seki, “Phototriggered Mass Migrating Motions in Liquid Crystalline Azobenzene Polymer Films with Systematically Varied Thermal Properties”, Macromolecules, 43, 4105-4112 (2010). |
| 43 |
S. Nagano, Y. Matsushita, S. Shinma, T. Ishizone, T. Seki, “Two dimensional nano-dot array engineering of block copolymer surface micelles on water surface”, Thin Solid Films, 518, 724-728 (2009). |
| 42 |
K. Nishizawa, S. Nagano, T. Seki, “Micropatterning of titanium oxide film via phototactic mass transport”, J. Mater. Chem., 19, 7191-7194 (2009). |
| 41 |
T. Seki, Y. Morikawa, T. Uekusa, S. Nagano, “Photoresponsive Liquid Crystals for Tuning and Aligning Nanostructures”, Molecular Cryst. Liquid Cryst., 510, 21-33 (2009). |
| 40 |
A. Toda, S. Nagano, T. Seki, “Ideal Spread Monolayer Formation and Surface Presure Induced Orientation in Poly(9,9’-di-n-octylfluorene-alt-benzothiadiazole) via Hybridization with Liquid Crystal Molecule on Water”, Syn. Met., 159 (9-10), 835-838 (2009). |
| 39 |
M. Sato, S. Nagano, T. Seki, “Photoresponsive Liquid Crystal Based on {(1-Cyclohexenyl) phenyldiazene} as a Close Analogue of Azobenzene”, Chem. Commun., 3792-3794 (2009). |
| 38 |
K. Nishizawa, S. Nagano, T. Seki, “Novel Liquid Crystalline Organic-Inorganic Hybrid for Highly Sensitive Photoinscriptions”, Chem. Mater., 21 (13), 2624-2631 (2009). |
| 37 |
W. Li, S. Nagano, T. Seki, “Photo-crosslinkable liquid-crystalline azo-polymer for surface relief gratings and persistent fixation”, New Journal of Chemistry, 33 (6), 1343-1348 (2009) (Top page cover featured). |
| 36 |
T. Uekusa, S. Nagano, T. Seki, “Highly Ordered In-Plane Photoalignment Attained by the Brush Architecture of Liquid Crystalline Azobenzene Polymer”, Macromolecules, 42(1), 312-318 (2009). |
| 35 |
S. Nagano, S. Kodama, T. Seki, Ideal Spread Monolayers and Multilayers Formation of Fully Hydrophobic Polythiophenes via Liquid Crystal Hybridization on Water, Langmuir, 24(18), 10498-10504 (2008). |
| 34 |
N. Zettsu, T. Ogasawara, N. Mizoshita, S. Nagano, T. Ubukata, T. Seki, “Photo-triggerred Surface Relief Gratings in Supramolecular Liquid Crystalline Polymer System with Detachable Azobenzene unit”, Adv. Mater., 20, 516 (2008). |
| 33 |
H. Murayama, A. B. Imran, S. Nagano, T. Seki, M. Kidowaki, K. Ito, Y. Takeoka, Chromonic Slide-Ring Gel Based on Reflection from Photonic Bandgap, Macromolecules, 41(5), 1808-1814 (2008). |
| 32 |
Y. Morikawa, T. Kondo, S. Nagano, T. Seki, “3D Photoalignment and Patterning of Microphase Separated Nanostructure in Polystyrene-Based Block Copolymer”, Chem. Mater., 19, 1540 (2007). |
| 31 |
T. Uekusa, S. Nagano, T. Seki, “Unique Molecular Orientation in a Smectic Liquid Crystalline Film Attained by Surface-Initiated Graft Polymerization”, Langmuir, 23, 4642 (2007). |
| 30 |
T. Sakai, H. Murayama, S. Nagano, Y. Takeoka, M. Kidowaki, K. Ito, T. Seki, “Photoresponsive Ring-Slide Gel”, Adv. Mater., 19, 2023 (2007). |
| 29 |
N. Zettsu, T. Ogasawara, R. Arakawa, S. Nagano, T. Ubukata, T. Seki, “Highly Photosensitive Surface Relief Gratings Formation in a Liquid Crystalline Azobenzene Polymer: New Implications for the Migration Process”, Macromolecules, 40(13), 4607-4613 (2007). |
| 28 |
M. Hara, S. Nagano, N. Mizoshita, T. Seki, “Chromonic/Silica Nanohybrids. Synthesis and Macroscopic Alignment”, Langmuir, 23, 12350 (2007). |
| 27 |
Y. Morikawa, T. Kondo, S. Nagano, T. Seki, “Optical Control of Microphase Separated Nanostructures in Polystyrene-Based Liquid Crystalline Diblock Copolymer Thin Films”, Transactions of the Materials Research Society Japan, 32, 363 (2007). |
| 26 |
A. Hozumi, S. Kojima, S. Nagano, T. Seki, N. Shirahata, T. Kameyama,“Surface Design for Precise Control of Spatial Growth of a Mesostructured Inorganic/Organic Film on a Large-Scale Area”, Langmuir, 23, 3265 (2007). |
| 25 |
S. Nagano, Y. Matsushita, Y. Ohnuma, S. Shinma, T. Seki, “Formation of highly ordered dot array of surface micelles of block copolymer via liquid crystal-hybridized self-assembly”, Langmuir, 22, 5233 (2006). |
| 24 |
Y. Morikawa, S. Nagano, K. Watanabe, K. Kamata, T. Iyoda, T. Seki, “Optical alignment and patterning of nanoscale microdomains in a block copolymer thin film”, Adv. Mater., 18, 883 (2006). |
| 23 |
H. Fukumoto, S. Nagano, N. Kawatsuki, T. Seki, “Photoalignment behavior of mesoporous silica thin films synthesized on a photo-crosslinkable polymer Film”, Chem. Mater., 18, 1226 (2006). |
| 22 |
H. Fukumoto, S. Nagano, T. Seki, “In situ polymerization of liquid crystalline monomers within photoaligned mesoporous silica thin film”, Chem. Lett., 35, 180-181 (2006). |
| 21 |
T. Uekusa, S. Nagano, T. Seki, “Sharp temperature dependency of 2D spreading behavior in amphiphilic block copolymer at the air-water interface”, Colloids and Surfaces A: Physicochem. Eng. Aspects, 284-285, 207-211 (2006). |
| 20 |
H. Fukumoto, S. Nagano, N. Kawatsuki, T. Seki, “Role of liquid crystallinity of the photo-crosslinkable polymer film in the photo-alignment of mesoporous silica”, Colloids and Surfaces A: Physicochem. Eng Aspects, 284-285, 309-314 (2006). |
| 19 |
S. Kadota, K. Aoki, S. Nagano, T. Seki, “Morphological conversions of nanostructures in monolayers of an ABA triblock copolymer having azobenzene moiety”, Colloids and Surfaces A: Physicochem. Eng. Aspects, 284-285, 535-541 (2006). |
| 18 |
T. Uekusa, S. Shinma, S. Nagano, T. Seki, “Temperature Dependenct Aggregation Behavior of Polystyrene-based Amphiphilic Block Copolymers at the Air-water Interface”, Transactions of the Materials Research Society Japan, 31(2), 265 (2006). |
| 17 |
Y. Morikawa, S. Nagano, K. Watanabe, K. Kamata, T. Iyoda, T. Seki, “Liquid Crystal-Assisted Photo-triggered Mass Migration in Liquid Crystalline Diblock Copolymer”, Transactions of the Materials Research Society Japan, 31(2), 269 (2006). |
| 16 |
S. Kadota, K. Aoki, S. Nagano, T. Seki, “Photocontrolled microphase separation of a block copolymer in two dimensions”, J. Am. Chem. Soc., 127, 8266 (2005). |
| 15 |
H. Fukumoto, S. Nagano, N. Kawatsuki, T. Seki, “Photo-orientation of mesoporous silica thin films on photocrosslinkable polymer films”, Adv. Mater., 17, 1035-1039 (2005). |
| 14 |
T. Seki, S. Nagano, Y. Kawashima, N. Zettsu, T. Ubukata, “Light-driven organized layer materials”, Mol. Cryst. Liq. Cryst, 430, 107-114 (2005). |
| 13 |
S. Nagano, T. Seki, “Ideal spread monolayer of fully hydrophobic polysilane, poly131(methyloctylsilane), with the assist of liquid crystal monolayer”, Trans. Mater. Res. Soc. Jpn., 30, 663 (2005). |
| 12 |
H. Fukumoto, S. Nagano, N. Kawatsuki, T. Seki, “Synthesis of photo-aligned mesoporous silica thin films on photo-crosslinkable polymer film”, Trans. Mater. Res. Soc. Jpn., 30, 361-364 (2005). |
| 11 |
S. Kadota, S. Nagano, T. Seki, “2D nanophase separation in monolayers of triblock copolymer having azobenzene moiety”, Trans. Mater. Res. Soc. Jpn., 30, 659-662 (2005). |
| 10 |
S. Nagano, T. Seki, “Abrupt interfacial transitions of hydrophobic polysilanes as probed via liquid crystal-assisted stepwise deposition”, J. Am. Chem. Soc., 124, 2074-2075 (2002). |
|---|---|
| 9 |
S. Nagano, T. Seki, K. Ichimura, “Conformational and alignment behavior of polysilane film mixed with liquid crystal molecule”, Mol. Cryst. Liq. Cryst., 367, 353-360 (2001). |
| 8 |
S. Nagano, T. Seki, K. Ichimura, “Monolayer formation of hydrophobic polysilane on water through hybridization with liquid crystal molecules”, Langmuir, 17, 2199-2205 (2001). |
| 7 |
S. Nagano, T. Seki, K. Ichimura, “Monolayer formation of hydrophobic polysilane on water surface assisted by liquid crystal molecule”, Chem. Lett., 612-613 (2000). |
| 6 |
永野修作, 関 隆広, 市村國宏, “ポリジヘキシルシランのコンフォメーションに及ぼす棒状液晶分子の添加効果”, 高分子論文集, 56, 406-409 (2000). |
| 5 |
K. Mochida, S. Nagano, “Electronic transport in phenyl-substituted polygermane homopolymers and copolymers with polygermanes and polysilanes”, Inorg. Chem. Commun., 1, 289-291 (1998). |
|---|---|
| 4 |
K. Mochida, S. Nagano, H. Kawata, M. Wakasa, H. Hayashi, “Micropattern of GeO2/GeC lines prepared by UV-irradiation and heat treatment of polygermane copolymers of methylphenylgermylene / phenylgermyne unit”, J. Applied Organomet. Chem., 11, 949-955 (1997). |
| 3 |
K. Mochida, S. Nagano, H. Kawata, M. Wakasa, H. Hayashi, “Photodegradation of thin films of polygermanes”, J. Organomet. Chem., 542, 75-79 (1997). |
| 2 |
K. Mochida, S. Nagano, S. Maeyama, T. Kodaira, A. Watanabe, O. Ito, M. Matsuda, “Nonlinear optical susceptibilities of oligo- and polygermanes”, Bull. Chem. Soc. Jpn., 70, 713-716 (1997). |
| 1 |
T. Kodaira, A. Watanabe, O. Ito, M. Matsuda, S. Tokura, M. Kira, S. Nagano, K. Mochida, “Third-order nonlinear optical properties of thin film of organogermane homopolymers and copolymer with organosilane”, Adv. Mater., 7, 917-918 (1995). |
Reviews
- 永野修作, “疎水性ポリシラン単分子膜と超薄膜”, ケイ素化学協会誌, 7, 16-19 (2003).
- 関 隆広, 川島康裕, 福本晴彦, 永野修作, “メソポーラス材料の光配向制御”, ゼオライト学会誌, 3, 73-79 (2004).
- Takahiro Seki, Shusaku Nagano, Nobuyuki Zettsu, Takashi Ubukata, "Liquid crystal-assisted engineering of polymer thin films", SPIE Proceedings, 5213, 154 (2003).
- 福本 晴彦, 永野 修作, 川月 喜弘, 関 隆広, “光配向製高分子液晶フィルムによるメソポーラスシリカ薄膜細孔配列の光配向---面内XRD測定による細孔配列方向の決定---”, 名古屋大学X線回折研究のあゆみ, 26, 3-6 (2005).
- 関 隆広, 永野修作, “ブロック共重合体ミクロ相分離構造の光制御”, 日本ゴム協会誌, 79, 237-243 (2006).
- 関 隆広・永野修作, フォトクロミズムを利用した２次元ナノ構造と配向の光制御, 機能材料, 27(8), 26-33 (2007).
- 原 光生・永野 修作・関 隆広, ポーラスシリカ薄膜, 多孔体の精密制御と機能・物性評価, サイエンス＆テクノロジー, 27-35 (2008).
- T. Seki, S. Nagano, “Light-Directed Dynamic Structure Formation and Alignment in Photoresponsive Thin Films”, Chem. Lett., 37(5), 484-489 (2008) (Highlight Review).
- Takahiro Seki; Mitsuo Hara; Haruhiko Fukumoto; Shusaku Nagano, "Photoalignment and patterning of nanostructures in liquid crystalline thin films ", SPIE Proceedings, 7050, 27 70500Y-1 (2008).(invited paper).
- 原 光生、永野 修作、関 隆広, リオトロピック液晶性色素のナノ構造体のシリカによる固定化と光配向, 名古屋大学X線回折研究のあゆみ, 30, 7-13 (2009).
- 関 隆広, 永野修作, “光を利用した高分子薄膜のメソ/ミクロ構造制御”, 光化学, 40, 188 (2009).
- 永野 修作, 並べるだけで全く別の材料に・・・－ポリエチレン鎖の配向・配列で熱伝導性が金属に匹敵 , 化学 , 65, 63-64 (2010).
- 関 隆広, 永野 修作, 界面作用に基づく薄膜の構造形成と配向誘起, 高分子, 60(9), 665-668 (2011).
- 永野 修作, 関 隆広, ミクロ相分離構造の光配向制御, 液晶, 15(4), 288-297 (2011).
- 戸田 章雄, 児玉 誠一郎, 永野 修作, 関 隆広, 疎水性共役高分子の新規分子組織化手法の開発と階層構造の構築, 名古屋大学X線回折研究のあゆみ, 31, 3-9 (2011)
- 原 光生, 土肥 知樹, 日影 達夫, 二村 佑樹, 永野 修作, 関 隆広, ラボスケールのGI-SAXS測定によるミクロ相分離構造の配向評価, 名古屋大学X線回折研究のあゆみ, 31, 17-21 (2011)
- 永野 修作, 原 光生, 関 隆広, 垂直配向メソ多孔構造膜の解析, 名古屋大学 電子光学研究のあゆみ, 23, 15-16 (2011).
- Shusaku Nagano, Opto-orientation control of microphase separation structure, Molecular Electronics and Bioelectronics, 22(2), 93-96 (2011)
- 関 隆広, 原 光生, 永野 修作, 界面を利用した高分子集合体の配向制御と構造形成, 表面, 50(5), pp.165-175 (2012).
- 福原 慶, 永野 修作, 関 隆広, 高分子液晶薄膜の光配向における空気界面の役割, 表面, 51(2), pp.22-32 (2013).
- 永野 修作, 関 隆広, 液晶性高分子薄膜の自由界面からの配向制御, 液晶, 19(1), 7-14 (2015).
- S. Nagano, “Inducing Planar Orientation in Side‐Chain Liquid‐Crystalline Polymer Systems via Interfacial Control”, Chem. Rec., 16, 378–392 (2016).
- 永野修作, 田中大介, “液晶高分子薄膜の分子配向と自由界面の影響”, C & I Commun, 41, 21-23 (2016).
著書
- 永野修作, "光機能性有機・高分子材料における新たな息吹 第5編 超薄膜とホストゲスト 第1章 液晶ブロック共重合体薄膜におけるミクロ相分離構造の動的光配向制御", シーエムシー(2019).
- 永野修作, 関 隆広,“光配向テクノロジーの開発動向 第3編 第2章 高分子超薄膜とナノ構造の光配向制御”, シーエムシー出版 (2010).
- 原 光生, 永野修作, 関 隆広,“光配向テクノロジーの開発動向 第4編 第2章 有機無機メソ組織体の光配向制御”, シーエムシー出版 (2010).
- 永野修作, 児玉 誠一郎, 戸田 章雄,“次世代共役ポリマーの超階層制御と革新機能 第2編 第12章 疎水性共役高分子の新規分子組織化手法の開発と界面超階層構造の構築”, シーエムシー出版 (2009).
- 永野修作, “光機能性高分子材料の新たな潮流 －最新技術とその展望－ 第5編 第4章 液晶相を利用したナノ構造体の光配向制御”, シーエムシー出版 (2008).
- 永野修作, 関 隆広, “有機薄膜形成とデバイス応用展開 第3章 疎水性共役高分子の単分子膜およびLangmuir-Blodgett 集積膜の形成”, シーエムシー出版 (2008).
- 永野修作, “ 3.5.3 光を用いた材料プロセッシング” 自然に学ぶ材料プロセッシング（共同執筆）, 196-206, 三共出版(2007)
- 永野修作, “機能物質の集積膜と応用展開 第4章 低分子にてアシストされた疎水性高分子の単分子膜展開法”, シーエムシー出版 (2006).
- 関 隆広、永野修作, “機能物質の集積膜と応用展開 第7章 二次元相分離パターンの形成と光制御”, シーエムシー出版 (2006).
【研究費】
- ナノ多孔質超薄膜の動的界面制御による応答性イオンダイオードの構築と整流特性制御, 研究代表者 石崎裕也, 若手研究, 課題番号22K14731, 2022年04月 ～ 2025年03月
- water command surface によるフレキシブル湿度センサー, 分担 永野, 研究代表者 松井淳, 挑戦的研究(萌芽), 課題番号22K18963, 2022年04月 ～ 2024年03月
- 「神経ネットワーク型分子・ナノ材料システム」研究代表者 松本卓也,-方向性ネットワーク構築-, CREST「原子・分子の自在配列・配向技術と分子システム機能」 2021年10月 ～ 2026年03月
- 液晶性高分子ラメラ構造に基づく光配向性機能材料の創出とナノデバイスへの展開, 研究代表者 永野修作, 科研費 基盤研究(B), 課題番号19H02774, 2019年04月 ～ 2022年03月
- ナノ相分離による非晶性ホモポリマーのラメラ構造化機構解明と超階層構造への展開, 分担 永野, 研究代表者 松井淳, 基盤研究(B), 課題番号18H02026, 2018年04月 ～ 2021年03月
- 液晶性高分子のヘテロスメクチックラメラ構造を用いたサブ10 nm微細構造形成 (財)東洋合成記念財団研究助成, 研究代表者 永野修作, 2016年4月～2017年3月
- 自由界面のトリガー効果に基づく高分子膜の増幅的変換プロセスの創出, 分担 永野, 研究代表者 関隆広, 基盤研究(S), 課題番号16H06355, 2016年4月 ～ 2021年3月
- 高分子高密度ブラシの自己集合形成手法の構築と応用 , 科研費 挑戦的萌芽研究, 研究代表者 永野修作, 課題番号15K13784, 2015年04月 ～ 2017年03月
- 高分子ナノ組織体に形成される2次元ナノ空間場を用いた超イオン伝導材料の創製, 分担 永野, 研究代表者 松井淳, 基盤研究(B), 課題番号26286010, 2014年04月 ～ 2018年03月
- ミクロ相分離構造の光配向技術に基づく新規デバイスナノ材料の創製, 研究代表者 永野修作, 科研費 基盤研究(B) , 課題番号25286025, 2013年04月 ～ 2016年03月
- 極微な領域規制に基づくメソ薄膜の形態発現と光応答系の創成, 分担 永野, 研究代表者 関隆広, 基盤研究(S), 課題番号23225003, 2011年4月 ～ 2016年3月
- 高分子ナノマテリアルの光アクティブ制御と機能探索, 研究代表者 永野修作, JST-さきがけ「ナノシステムと機能創発」, 2009年10月 ～ 2013年3月
- ハイドロゲル表面への光応答基の導入と吸着特性の光制御, 研究代表者 永野修作, JSTシーズ発掘試験 , 2008年04月 ～ 2009年03月
- 2次元の分子自己集合に基づく光メカニカル機能発現と応用, 分担 永野, 研究代表者 関隆広, 科研費 特定領域研究「フォトクロミズムの攻究とメカニカル機能の創出」, 課題番号19050005, 2007年4月~2011年3月
- ブロック共重合体単分子膜を利用したナノ相分離構造のマニピュレーション, 研究代表者 永野修作, 科研費 若手研究B , 課題番号18710096, 2006年4月 ～ 2009年3月
- 疎水性共役高分子の新規分子組織化手法の開発と界面超階層構造の構築, 研究代表者 永野修作, 科研費 特定領域研究「次世代共役ポリマーの超階層制御と革新機能」（公募），課題番号19022014 , 2007年 ～ 2008年
- 疎水性共役高分子の単分子膜マニピュレーションと界面超階層構造構築, 研究代表者 永野修作, 科研費 特定領域研究「次世代共役ポリマーの超階層制御と革新機能」（公募）, 課題番号18039016, 2006年 ～ 2007年
- ブロック共重合体単分子膜を用いた高信頼性ナノドットアレイ形成と高密度光記録媒体, 研究代表者 永野修作, (財)村田学術振興財団研究助成 ,2005年07月 ～ 2006年07月
- 階層構造を持つ光誘起物質移動システムの構築とコンベア型描画法の開発, 分担 永野, 研究代表者 関隆広, 科研費 基盤研究(A), 課題番号16205019, 2004年4月~2007年3月
